How to prepare for ISEET 2014
“Learn the fundamental concepts of Physics,
Chemistry and Mathematics”: - everybody says that “learn fundamental concepts to
crack any competitive exams, learn basic concepts. Don’t just remember, or
mugup the things.” but do u know what is exactly meaning of “learning the
fundamentals and basics” Let’s
see what is the meaning
of learning the concepts.
For example if you are learning about equivalent no.,
equivalent wt. Normally most students think that always equivalent wt. Of H2SO4
is 49. If you are thinking the same, means your concepts also not clear. It is not
always 49.
Let’s clear the concept
Equivalent wt =
molecular wt. / n factor
Now n factor for acids = basicity of acids (no. Of
total replaceable H+ ion)
Because there are two H in H2SO4 are
replaceable. Its n factor is 2.
So eq. Wt = 98/2 =49
But it is always not true. n factor also depend on
chemical reaction. If in any reaction H2SO4 only donate 1
H+ ion and gets converted into HSO4- for example :-
NaOH + H2SO4 →NaHSO4
+ H2O
In the above reaction H2SO4 only donating 1 H+. So here n
factor for H2SO4 is one 1. So eq.wt = 98/1= 98 in this
reaction
But in the following reaction
2 NaOH + H2SO4 →Na2SO4
+ 2H2O
H2SO4 donate its all 2 H+
ion and gets converted into SO4-2 ion. So in
this reaction n factor for H2SO4 is 2. So eq. Wt of H2SO4
in this reaction = 98/2 = 49.
Because H2SO4 have total
2 H+ to donate. So generally we assume that it is donating its all
two H+. Hence generally we consider n factor for H2SO4
is two. But if in the question there is any reaction of H2SO4
is given then carefully see the reaction whether it is donating 1 or two H+.
According to that your ans. of eq.wt. of H2SO4 would be
98 or 49. But if there is no such reaction of H2SO4 is
given then we assume that H2SO4
is donating its all two H+ ion so n factor is assumed
two and eq.wt is 49.
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