Wednesday 17 July 2013

SOLID STATE "BRAVAIS LATTICE"


The three Bravais lattices which form cubic crystal systems are:

Cubic Bravais lattices
Name Primitive cubic Body-centered cubic Face-centered cubic
Pearson symbolcPcIcF
Unit cell Lattic simple cubic.svg Lattice body centered cubic.svg Lattice face centered cubic.svg
The primitive cubic system (cP) consists of one lattice point on each corner of the cube. Each atom at a lattice point is then shared equally between eight adjacent cubes, and the unit cell therefore contains in total one atom (18 × 8).
The body-centered cubic system (cI) has one lattice point in the center of the unit cell in addition to the eight corner points. It has a net total of 2 lattice points per unit cell (18 × 8 + 1).
The face-centered cubic system (cF) has lattice points on the faces of the cube, that each gives exactly one half contribution, in addition to the corner lattice points, giving a total of 4 lattice points per unit cell (18 × 8 from the corners plus 12 × 6 from the faces).









The 7 lattice systems The 14 Bravais lattices
Triclinic P
Triclinic
Monoclinic P C
Monoclinic, simple Monoclinic, centred
Orthorhombic P C I F
Orthohombic, simple Orthohombic, base-centred Orthohombic, body-centred Orthohombic, face-centred
Tetragonal P I
Tetragonal, simple Tetragonal, body-centred
Rhombohedral P
Rhombohedral
Hexagonal P
Hexagonal
Cubic P (pcc) I (bcc) F (fcc)
Cubic, simple Cubic, body-centred Cubic, face-centred







Lattice System Possible Variations Axial Distances (edge lengths) Axial Angles Examples
Cubic Primitive, Body-centred, Face-centred a = b = c α = β = γ = 90° NaCl, Zinc Blende, Cu
Tetragonal Primitive, Body-centred a = b ≠ c α = β = γ = 90° White tin, SnO2, TiO2, CaSO4
Orthorhombic Primitive, Body-centred, Face-centred, Base-centred a ≠ b ≠ c α = β = γ = 90° Rhombic sulphur, KNO3, BaSO4
Hexagonal Primitive a = b ≠ c α = β = 90°, γ = 120° Graphite, ZnO, CdS
Rhombohedral Primitive a = b = c α = β = γ ≠ 90° Calcite (CaCO3, Cinnabar (HgS)
Monoclinic Primitive, Base-centred a ≠ b ≠ c α = γ = 90°, β ≠ 90° Monoclinic sulphur, Na2SO4.10H2O
Triclinic Primitive a ≠ b ≠ c α ≠ β ≠ γ ≠ 90° K2Cr2O7, CuSO4.5H2O, H3BO3









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